Multiple bonding in unbridged Mn-Mn dimers of solid-state nitridomanganate(IV) oxide Ca6[Mn2N6]O

N. Buschmann; Dominik Werhahn; Simon Steinberg; Clemens Ritter; Paul Attfield; Simon D. Kloß

doi:10.1039/d5cc04348d

January 1, 2025Chemical CommunicationsOpen Access

Multiple bonding in unbridged Mn-Mn dimers of solid-state nitridomanganate(IV) oxide Ca6[Mn2N6]O

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Key Points

Unbridged metal-metal bonding occurs in Ca6[Mn2N6]O, highlighting an uncommon structure in solid-state materials.
Calcium nitridomanganate(IV) oxide features [MnN3]2 dimers, presenting potential new chemistry in oxides.
Study involved characterizing unique dimers formed via solid-state synthesis methods, advancing understanding of metal bonding.
Highlights the need for further research into the implications of these nitridomanganate structures and their stability.

Implication

Research reveals unbridged metal-metal bonding in nitridomanganate, suggesting unique structural properties.

Abstract

Unbridged metal-metal bonding is rare in solid-state materials owed to preferred coordination of metals through main group anions. Here, we present a calcium nitridomanganate(IV) oxide Ca6[Mn2N6]O with [MnN3]2 dimers prepared...

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Cite This Study

Buschmann et al. (2025) studied this question.

synapsesocial.com/papers/68c198cd9b7b07f3a061ab6e https://doi.org/10.1039/d5cc04348d

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Multiple bonding in unbridged Mn-Mn dimers of solid-state nitridomanganate(IV) oxide Ca6[Mn2N6]O

Key Points

Implication

Abstract

Discussion

Cite This Study

Multiple bonding in unbridged Mn-Mn dimers of solid-state nitridomanganate(IV) oxide Ca6[Mn2N6]O

Key Points

Implication

Abstract

Discussion

Cite This Study

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