A La-containing poly(polyoxometalate) simultaneously comprising tungstoantimonate and tungstobismuthate segments: synthesis, structure and catalytic property

A novel La-containing octameric polyoxotungstate [H2N(CH3)2]8Na12H16[{(WO2)2(WO3)2(B-β-BiW9O33)2}{Bi6O3(OH)3La3(H2O)6 (CO3)(B-α-SbW9O33)3}2]∙52H2O (1) has been synthesized under the weakly acidic aqueous solution conditions, and further structurally characterized by single-crystal X-ray diffraction, powder X-ray diffraction, IR...