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January 1, 2025Dalton TransactionsOpen Access

Thio-iso-phthalamide Pincer Ligands Driven Oxidative Addition of a C-Br Bond to Gold(I): Synthesis and Studies of SCS-Gold(III) Pincer Complexes

Saravanan Raju Sanhati Sharangi Harkesh B. Singh Prabhuraj R.S.Rohit Srivastava Ray J. Butcher Sangit Kumar

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Key Points

The study successfully demonstrates the oxidative addition of the aryl Csp²-Br bond to Gold(I), facilitating the formation of stable complexes.
Significant findings include the isolation of stable SCS·Au(III)X complexes, showcasing the effectiveness of thio-iso-phthalamide as a ligand.
The experimental approach involved synthesizing SMe₂Au(I)Cl salt, which was crucial for the oxidative addition process.
These results suggest new pathways for advanced Gold(III) complex synthesis utilizing chelating ligands.

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Implication

This research explores the oxidative addition mechanism in Gold(I) with thio-iso-phthalamide ligands, revealing new SCS-Gold(III) complexes.

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Cite This Study

Raju et al. (2025) studied this question.

synapsesocial.com/papers/68c1a13354b1d3bfb60dc842 https://doi.org/10.1039/d5dt00916b

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