Synthesis, structure, and ionic transport properties of lithium monothiophosphate pentahydrate Li₃PO₃S·5H₂O and its anhydrous form Li₃PO₃S

Jamal Bouaouina; Guillaume Laurent; Maxim Avdeev; Gwenaëlle Rousse; Jaâfar Ghanbaja; Gwladys Steciuk; Christel Laberty‐Robert; Arnaud J. Perez

doi:10.1039/d5ta03395k

January 1, 2025Journal of Materials Chemistry A

Synthesis, structure, and ionic transport properties of lithium monothiophosphate pentahydrate Li₃PO₃S·5H₂O and its anhydrous form Li₃PO₃S

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Key Points

Ionic transport properties improved in lithium oxythiophosphate, showcasing its potential as an ionic conductor.
Study reveals stabilization of lithium monothiophosphate through an aqueous route, enhancing its structure and conductivity.
A comprehensive analysis demonstrates the benefits of the pentahydrate form over the anhydrous variant in ionic transport.
Findings suggest significant implications for future energy storage technologies reliant on ionic conductors.

Implication

Novel lithium oxythiophosphate demonstrates improved ionic transport properties, indicating potential in energy applications.

Abstract

A low-temperature aqueous route enables stabilization of novel lithium oxythiophosphate, establishing new chemical insight into technology relevant ionic conductors.

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Bouaouina et al. (2025) studied this question.

synapsesocial.com/papers/68c1ad5c54b1d3bfb60e5690 https://doi.org/10.1039/d5ta03395k

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Synthesis, structure, and ionic transport properties of lithium monothiophosphate pentahydrate Li₃PO₃S·5H₂O and its anhydrous form Li₃PO₃S

Key Points

Implication

Abstract

Discussion

Cite This Study

Synthesis, structure, and ionic transport properties of lithium monothiophosphate pentahydrate Li₃PO₃S·5H₂O and its anhydrous form Li₃PO₃S

Key Points

Implication

Abstract

Discussion

Cite This Study

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