Reaction Mechanism of Silylation of C−O Bonds in Alkyl Ethers over Supported Gold Catalysts: Experimental and Theoretical Investigations

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This is a Observational study (also classified as: Animal Study).

Yunosuke Tsunesada; Tatsushi Ikeda; Koki Muraoka; Masafumi Doi; Hiroki Miura; Tetsuya Shishido; Akira Nakayama

doi:10.1039/d5cp01973g

January 1, 2025Physical Chemistry Chemical Physics

Reaction Mechanism of Silylation of C−O Bonds in Alkyl Ethers over Supported Gold Catalysts: Experimental and Theoretical Investigations

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Key Points

The study reveals a detailed reaction mechanism for silylation of C−O bonds.
Experimental analysis shows the role of α-Fe2O3-supported gold catalysts enhances ether activation.
Computational approaches complement experimental findings, offering deeper insights into silylation pathways.
The findings suggest that optimizing gold catalysts can improve reactions involving alkyl ethers.

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Implication

Experimental and theoretical investigations unveil silylation mechanisms in alkyl ethers, indicating gold catalysts' efficacy.

Abstract

The reaction mechanism of α -Fe 2 O 3 -supported Au-catalyzed silylation of ether C(sp 3 )–O bonds by disilane is investigated using both experimental and computational approaches. The experimental study reveals that the ether activation is...

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Tsunesada et al. (2025) studied this question.

synapsesocial.com/papers/68c1ad6a54b1d3bfb60e5c5a https://doi.org/10.1039/d5cp01973g

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Reaction Mechanism of Silylation of C−O Bonds in Alkyl Ethers over Supported Gold Catalysts: Experimental and Theoretical Investigations

Key Points

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Implication

Abstract

Discussion

Cite This Study

Reaction Mechanism of Silylation of C−O Bonds in Alkyl Ethers over Supported Gold Catalysts: Experimental and Theoretical Investigations

Key Points

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Implication

Abstract

Discussion

Cite This Study

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