Relation Between Diffusion Equations and Boundary Conditions in Bounded Systems

Differential equations need boundary conditions (BCs) for their solution. It is widely acknowledged that differential equations and BCs are representative of independent physical processes, and no correlations between them are required. Two recent studies by Hilhorst, Chung et al. argue instead that, in the specific case of diffusion equations (DEs) in bounded systems, BCs are uniquely constrained by the form of transport coefficients. In this paper, we revisit how DEs emerge as fluid limits out of a picture of stochastic transport. We point out their limits of validity and argue that, in most physical systems, BCs and DEs are actually uncorrelated by virtue of the failure of diffusive approximation near the system’s boundaries. When, instead, the diffusive approximation holds everywhere, we show that the correct chain of reasoning goes in the direction opposite to that conjectured by Hilhorst and Chung: it is the choice of the BCs that determines the form of the DE in the surroundings of the boundary.