The Dichotomous Behavior of Allylsilanes in the Additions to Platinum α,β-Unsaturated Carbenes

Jeff P. Costello; Jacob P Garber; Khoi Huynh; Eric M. Ferreira

doi:10.1039/d5sc03784k

January 1, 2025Chemical ScienceOpen Access

The Dichotomous Behavior of Allylsilanes in the Additions to Platinum α,β-Unsaturated Carbenes

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Key Points

The allylsilanes exhibit dual reactivity, leading to different reaction pathways depending on the conditions.
Under nonpolar conditions, a specific (3+2) cycloaddition occurs, highlighting catalytic control.
The nature of catalytic conditions significantly influences the behavior of allylsilanes in reactions.
Understanding the reaction pathways may enable better applications of platinum in synthetic organic chemistry.

Implication

Observational analysis reveals allylsilanes exhibit dual reactivity with platinum α,β-unsaturated carbenes, suggesting varied reaction pathways.

Abstract

The observation of allylsilane dual reactivity with α,β-unsaturated platinum carbenes is described. The reaction pathways are controlled by the nature of the catalytic conditions. Under nonpolar conditions, a (3+2) cycloaddition...

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Cite This Study

Costello et al. (2025) studied this question.

synapsesocial.com/papers/68c1d5fe54b1d3bfb60f92a8 https://doi.org/10.1039/d5sc03784k

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The Dichotomous Behavior of Allylsilanes in the Additions to Platinum α,β-Unsaturated Carbenes

Key Points

Implication

Abstract

Discussion

Cite This Study

The Dichotomous Behavior of Allylsilanes in the Additions to Platinum α,β-Unsaturated Carbenes

Key Points

Implication

Abstract

Discussion

Cite This Study

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