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September 16, 2025Advanced Sustainable SystemsOpen Access

Aqueous Synthesis of UiO‐66 Metal‐Organic Frameworks With Enhanced Crystallinity and Surface Area

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Authors

NSNandish Hosadoddi SrikantamurthyJOJoseph F. OlorunyomiCDCara M. Doherty

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Overview

This research reveals high crystallinity and surface area in MOFs using green chemistry approaches, suggesting enhanced real-world application potential.

Key Points

  • The novel aqueous synthesis method produced UiO-66(Zr) MOFs with a surface area of 741 m2 g−1, outperforming previous methods.
  • This approach allows for the use of benign solvents, addressing the need for more sustainable synthesis in the production of MOFs.
  • By varying NaOH concentration and maintaining specific conditions, superior crystallinity in MOF particles was achieved.
  • The inclusion of ethanol as a recyclable solvent in the purification process enhances scalability and sustainability in MOF production.

Cite This Study

Srikantamurthy et al. (2025) studied this question.

synapsesocial.com/papers/68d454d831b076d99fa5ac92https://doi.org/10.1002/adsu.202500854
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Also Consider

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  1. 1A water-based synthetic route to metal-organic framework UiO-66 starting from PET-derived terephthalate esters2025
  2. 2Introducing functionalities into directly synthesised amorphous UiO-66-based metal-organic frameworks2026 · 2 citations
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  4. 4Design and Fabrication of Metal-Organic Framework UiO-66 Membranes for Advanced Separation2026
  5. 5Direct Synthesis of High‐Valence Protein@UiO‐66 Composites: Linking Crystallization Pathways to Protein Encapsulation2026 · 2 citations