Bulky Bis-Guanidine Ligand Based Neutral and Cationic Zinc Alkyl, Halide, and Hydride Complexes: Synthesis, Characterization, and Catalytic Application

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This is a Experimental Study study.

Rajata Kumar Sahoo; Sayantan Mukhopadhyay; Sagrika Rajput; Achintya Jana; Sharanappa Nembenna

doi:10.1039/d4dt02907k

January 1, 2025Dalton TransactionsOpen Access

Bulky Bis-Guanidine Ligand Based Neutral and Cationic Zinc Alkyl, Halide, and Hydride Complexes: Synthesis, Characterization, and Catalytic Application

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Key Points

The synthesized zinc complexes show effective catalytic properties in various applications, enhancing their usefulness.
Characterization of the complexes reveals important structural insights into their alkyl, halide, and hydride forms.
The bulky bis-guanidine ligand facilitates the unique formation of these zinc complexes, indicating its significance in synthesis.
The study highlights how these complexes could play a role in future catalytic systems, opening up new avenues for research.

Implication

This research reveals the synthesis of zinc alkyl and halide complexes, suggesting their potential for catalytic applications.

Abstract

The tetra-aryl substituted bis-guanidine ligand L(3H) (L(3H) = {(ArHN)(ArNH)-C=N-C=(NAr)(NHAr)}; Ar=2,6-iPr2-C6H3), was used for the synthesis of mononuclear zinc(II) alkyls [L(2H)ZnR, R = Me (Zn-1), Et (Zn-2)], iodide [L(2H)ZnI, (Zn-3)], hydride...

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Sahoo et al. (2025) studied this question.

synapsesocial.com/papers/68d45e5831b076d99fa5e97a https://doi.org/10.1039/d4dt02907k

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Bulky Bis-Guanidine Ligand Based Neutral and Cationic Zinc Alkyl, Halide, and Hydride Complexes: Synthesis, Characterization, and Catalytic Application

Key Points

Implication

Abstract

Discussion

Cite This Study

Bulky Bis-Guanidine Ligand Based Neutral and Cationic Zinc Alkyl, Halide, and Hydride Complexes: Synthesis, Characterization, and Catalytic Application

Key Points

Implication

Abstract

Discussion

Cite This Study

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