Manganese germylene hydride complexes: reactivity with carbon dioxide, benzophenone, and diisopropylcarbodiimide

Q: What type of study is this?

This is a Experimental Study study.

Jeffrey S. Price; David J. H. Emslie

doi:10.1039/d5dt01701g

January 1, 2025Dalton TransactionsOpen Access

Manganese germylene hydride complexes: reactivity with carbon dioxide, benzophenone, and diisopropylcarbodiimide

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Key Points

Reactions of manganese germylene hydride complexes with carbon dioxide produce formate-substituted complexes.
The study describes the creation of κ2-formatogermyl complexes from interacting with CO2 and other unsaturated substrates.
Experimental analysis shows reactivity towards a ketone and a carbodiimide, demonstrating diverse chemical behavior.
Findings suggest new avenues for exploring manganese-based complexes in synthetic chemistry.

Implication

Observational analysis reveals manganese germylene hydride complexes react with CO2 and related compounds, indicating novel complex formation.

Abstract

Reactions of manganese germylene hydride complexes with CO 2 are described, affording formate-substituted germylene and κ 2 -formatogermyl complexes. Reactions with related unsaturated substrates (a ketone and a carbodiimide) are also discussed.

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Cite This Study

Price et al. (2025) studied this question.

synapsesocial.com/papers/68d466a831b076d99fa64dd6 https://doi.org/10.1039/d5dt01701g

View Full Paper

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Manganese germylene hydride complexes: reactivity with carbon dioxide, benzophenone, and diisopropylcarbodiimide

Key Points

Implication

Abstract

Discussion

Cite This Study

Manganese germylene hydride complexes: reactivity with carbon dioxide, benzophenone, and diisopropylcarbodiimide

Key Points

Implication

Abstract

Discussion

Cite This Study

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