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September 19, 2025Analytical Chemistry3 citations

A Modular DNA-Assembled Nanopipette (mDNP) Platform for Spatially Confined Single-Cell Nuclear Detection of Methyltransferase Activity

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JSJuan SongCXChengqiang XiaXZXian Zhang

Key Points

  • The mDNP platform detects DNMT1 activity with high sensitivity and analytical precision.
  • This system can quantitatively evaluate DNMT1 inhibition in both malignant and nonmalignant cells.
  • It uses rolling circle amplification to produce ionic current signals for methylation detection.
  • The device allows for single-cell epigenetic profiling, useful for inhibitor screening.

Abstract

Single-cell epigenetic regulation relies on spatially organized enzymatic activities within nuclear compartments, which establish DNA methylation patterns that dictate gene expression and cellular identity. Given this spatial organization, we present a modular DNA-assembled nanopipette (mDNP) platform for ultrasensitive detection of DNA methyltransferase 1 (DNMT1) within the nucleus of individual cells. The device incorporates tripartite DNA molecular sentinel probes that undergo methylation-dependent sequence discrimination and initiate rolling circle amplification, producing quantifiable ionic current signals within a confined nanofluidic interface. This system offers high analytical precision and a broad linear range, enabling quantitative evaluation of DNMT1 inhibition and differentiation between malignant and nonmalignant cell populations. The regenerable mDNP device provides an integrated platform for single-cell epigenetic profiling and inhibitor screening at subcellular resolution.

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Cite This Study

Song et al. (2025) studied this question.

synapsesocial.com/papers/68d466af31b076d99fa65374https://doi.org/10.1021/acs.analchem.5c04747
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