Stabilization of the cubic π-phase of SnS by calcium substitution

Neeraj Mishra; Susmita Paul; Lonia Friedlander; Yuval Golan; Guy Makov

doi:10.1039/d5qm00399g

January 1, 2025Materials Chemistry FrontiersOpen Access

Stabilization of the cubic π-phase of SnS by calcium substitution

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Key Points

Calcium substitution stabilizes the cubic π-phase of SnS, enhancing its properties.
Smaller amounts of Ca are needed than the expected computational values, demonstrating adsorption effects.
The study shows that Ca plays a dual role in stabilizing SnS, combining bulk effects with surface interactions.
Findings on cubic SnS offer insights for future materials design and application in various technologies.

Implication

Experimental results reveal calcium enhances cubic SnS stability, indicating its role in adsorption.

Abstract

The metastable cubic phase π-SnS can be stabilized by calcium substitution. Smaller amounts of Ca are observed experimentally compared to the computationally required amounts, pointing to the role of Ca adsorption in addition to bulk stabilization.

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Cite This Study

Mishra et al. (2025) studied this question.

synapsesocial.com/papers/68d7b3edeebfec0fc5237319 https://doi.org/10.1039/d5qm00399g

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Stabilization of the cubic π-phase of SnS by calcium substitution

Key Points

Implication

Abstract

Discussion

Cite This Study

Stabilization of the cubic π-phase of SnS by calcium substitution

Key Points

Implication

Abstract

Discussion

Cite This Study

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