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September 27, 2025Open Access

Prospects for forming C–N bonds from dinitrogen

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This perspective outlines success in forming C–N bonds using dinitrogen and transition metal complexes, suggesting pathways for nitrogen utilization.

Catalytic formation of C–N bonds from dinitrogen presents a novel synthetic route for nitrogen-containing compounds.
Recent advances include various coordination modes for activating dinitrogen with transition metal complexes.
Reactivity of reduced nitrogen intermediates varies with different carbon sources, enhancing bond formation methods.
Cycloaddition reactions with polarized dinitrogen and carbon electrophiles can lead to complex nitrogen-containing products.

Hidalgo et al. (2025) studied this question.

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September 27, 2025Open Access

View Full Paper

Ask AI

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Authors

This perspective outlines success in forming C–N bonds using dinitrogen and transition metal complexes, suggesting pathways for nitrogen utilization.

Catalytic formation of C–N bonds from dinitrogen presents a novel synthetic route for nitrogen-containing compounds.
Recent advances include various coordination modes for activating dinitrogen with transition metal complexes.
Reactivity of reduced nitrogen intermediates varies with different carbon sources, enhancing bond formation methods.
Cycloaddition reactions with polarized dinitrogen and carbon electrophiles can lead to complex nitrogen-containing products.

Hidalgo et al. (2025) studied this question.

View Full Paper

Ask AI

Bookmark