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September 28, 2025ACS Omega3 citationsOpen Access

Advanced Epoxy Polymer Composite Design: Maximizing Fracture Toughness and Piezoelectric Effect with Core–Shell Rubber and Barium Titanate Particles

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MYM YasarBSBerran SanayCDCormac Duffy

Key Points

  • The incorporation of 5 wt % core–shell rubber significantly raised fracture energy from 465 to 2213 J/m2.
  • A maximum open circuit voltage output of 1.85 V was recorded with 15 wt % core–shell rubber addition.
  • Testing included tensile, single lap shear, and T-Peel strength assessments to determine mechanical properties.
  • Dynamic mechanical analysis provided insights into the thermal-mechanical behavior of the composites.

Abstract

Epoxy resins, when cured are important thermoset polymers which possess exceptional bonding strength, versatility, and resistance, making them indispensable in various industries ranging from construction to electronics. This study aims to investigate epoxy-based polymer composites with varying core–shell rubber (CSR) fractions (0–5–10–15–25 wt %) with a fixed weight percentage (20 wt %) of barium titanate (BaTiO3) and tailor the thermal, mechanical and piezoelectric behavior of the resulting materials. Tensile, single lap shear and T-Peel strength tests were conducted to evaluate the effects of CSR and BaTiO3 additives on the mechanical properties of the composites. Fracture toughness and fracture energy measurements were performed using the single-edge notched bend test to assess the crack resistance of the composites. The thermal-mechanical properties of the composites were analyzed using a dynamic mechanical analyzer. A voltage output test was performed to evaluate the piezoelectric properties of the composites. The results demonstrated that with 5 wt % CSR incorporation, the composite exhibited a remarkable increase in fracture energy, increasing from 465 to 2213 J/m2, and with 15 wt % CSR addition, the highest open circuit voltage output of 1.85 V was obtained.

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Cite This Study

Yasar et al. (2025) studied this question.

synapsesocial.com/papers/68d9051441e1c178a14f48d7https://doi.org/10.1021/acsomega.5c03542
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