Diels-Alder Reaction of Substituted Cyclopentadienones with Benzothiophene S, S-dioxides: Synthesis of Dibenzothiophenes, Dibenzothiophene S, S-dioxides, Acenaphthenes, Phenanthrenes, Pyrenes, and Fluorenones by Exploiting Thermolysis of Diels-Alder Adducts

Q: What type of study is this?

This is a Experimental Study study.

D. K.; MANIKANDAN Palani; Arasambattu K. Mohanakrishnan

doi:10.1039/d5qo00797f

January 1, 2025Organic Chemistry Frontiers

Diels-Alder Reaction of Substituted Cyclopentadienones with Benzothiophene S, S-dioxides: Synthesis of Dibenzothiophenes, Dibenzothiophene S, S-dioxides, Acenaphthenes, Phenanthrenes, Pyrenes, and Fluorenones by Exploiting Thermolysis of Diels-Alder Adducts

View at Publisher

Ask AI

Bookmark

Share

Key Points

Diels-Alder reaction formed multiple aromatic compounds, yielding diverse products like dibenzothiophenes.
Key products include acenaphthenes, phenanthrenes, and fluorenones, with varying solvent effects noted.
This approach utilized thermolysis of Diels-Alder adducts to enhance product diversity and optimize synthesis.
Findings highlight the reaction's potential for synthesizing complex aromatic structures in organic chemistry.

Implication

Diels-Alder reaction produced dibenzothiophenes and phenanthrenes from cyclopentadienones, indicating its synthetic versatility.

Abstract

Diels-Alder (DA) reaction of a series of tetra substituted cyclopentadienones (CPDs) with benzo[b]thiophene S, S-dioxide analogues in various solvents at different temperatures led to the formation carbocyclic as well as...

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

K. et al. (2025) studied this question.

synapsesocial.com/papers/68dd91dafe798ba2fc49934f https://doi.org/10.1039/d5qo00797f

View at Publisher

Ask AI

Bookmark

Share

Diels-Alder Reaction of Substituted Cyclopentadienones with Benzothiophene S, S-dioxides: Synthesis of Dibenzothiophenes, Dibenzothiophene S, S-dioxides, Acenaphthenes, Phenanthrenes, Pyrenes, and Fluorenones by Exploiting Thermolysis of Diels-Alder Adducts

Key Points

Implication

Abstract

Discussion

Cite This Study

Diels-Alder Reaction of Substituted Cyclopentadienones with Benzothiophene S, S-dioxides: Synthesis of Dibenzothiophenes, Dibenzothiophene S, S-dioxides, Acenaphthenes, Phenanthrenes, Pyrenes, and Fluorenones by Exploiting Thermolysis of Diels-Alder Adducts

Key Points

Implication

Abstract

Discussion

Cite This Study

Keep reading

More related papers

More from Organic Chemistry Frontiers

Keep reading

More related papers

More from Organic Chemistry Frontiers