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This is a Quantitative Study study.

Unraveling Steric and Dispersion Effects in Gold Catalysis: A DFT Study of Asymmetric Cyclization/Mannich Reactions

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DFT study examines gold catalysis with chiral phosphoric acids for efficient asymmetric reactions, suggesting enhanced enantioselectivity.

The study reveals significant steric and dispersion effects in gold catalysis, enhancing reaction outcomes.
Key findings indicate high enantioselectivity in asymmetric cyclization/Mannich reactions using gold complexes.
Utilizing DFT analysis provides insights into the cooperative mechanisms of gold complexes and chiral phosphoric acids.
The findings underline the potential of gold catalysis for producing chiral spiroindolenines efficiently.

Li et al. (2025) studied this question.

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DFT study examines gold catalysis with chiral phosphoric acids for efficient asymmetric reactions, suggesting enhanced enantioselectivity.