Thermally-Driven Conformational Twist in Organic Azobenzene Linker Activates Molecular Doping Effect in Thin Films of Lanthanide MOFs

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This is a Experimental Study study.

Umashis Bhoi; Mini Kalyani; K. S. Ananthram; Sauvik Saha; Aradhana Acharya; Nahid Hassan; Moses Sam Arul Raj; Kartick Tarafder; Nirmalya Ballav

doi:10.1039/d5ta05740j

January 1, 2025Journal of Materials Chemistry AOpen Access

Thermally-Driven Conformational Twist in Organic Azobenzene Linker Activates Molecular Doping Effect in Thin Films of Lanthanide MOFs

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Key Points

The study reveals that conformational changes in azobenzene promote molecular doping in lanthanide MOFs, enhancing their functionality.
Results indicate that thermal stimulation leads to significant modifications in the thin films, promoting better performance in applications.
Employing azobenzene in MOFs was assessed through detailed structural analyses, revealing its effectiveness as a photo-switchable component.
This finding may facilitate advances in smart materials, indicating new applications for MOFs in various technological fields.

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Implication

This analysis demonstrates enhanced molecular doping in thin films of lanthanide MOFs, highlighting azobenzene's role in stimuli-responsive systems.

Abstract

Azobenzene-based photo-switchable molecules have shown significant potential in stimuli-responsive systems, especially when incorporated into metal-organic frameworks (MOFs). This study reports thin films of lanthanide-based metal-organic frameworks (Ln-MOFs) with 4,4′-azobenzene dicarboxylic...

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Bhoi et al. (2025) studied this question.

synapsesocial.com/papers/68de68ea83cbc991d0a214ae https://doi.org/10.1039/d5ta05740j

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Thermally-Driven Conformational Twist in Organic Azobenzene Linker Activates Molecular Doping Effect in Thin Films of Lanthanide MOFs

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Implication

Abstract

Discussion

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Thermally-Driven Conformational Twist in Organic Azobenzene Linker Activates Molecular Doping Effect in Thin Films of Lanthanide MOFs

Key Points

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Implication

Abstract

Discussion

Cite This Study

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