The generation of long-chain alkoxy radicals via visible light-induced energy transfer (EnT) has been accomplished through the design of a new class of bifunctional oxime esters derived from iminophenylacetic acid. The 1,5-hydrogen atom abstraction (HAT) of the alkoxy radicals, followed by alkylamination of alkenes, enables the construction of a 1,6-linkage across a double bond to achieve the valuable 1,6-amino alcohols.
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Sun et al. (2024) studied this question.
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