Stimulated Raman scattering of a broadband chirped Ti:sapphire laser pulse in calcite seeded by a narrowband nanosecond Nd:YAG laser pulse

Stimulated Raman Scattering (SRS), pumped by a broadband (i.e., compared to the bandwidth of the material excitation) chirped 50-ps pulse, with Stokes seeding by a 20-ns narrowband pulse, is experimentally and theoretically investigated. In the experiments, a femtosecond-class 0.95 μm Ti:sapphire laser system and a Q-switched 1.064 μm Nd:YAG laser were used for pumping and seeding SRS in a calcite (CaCO3) crystal. This material was chosen because its Raman resonance frequency (∼1089 cm−1) is near to the frequency difference between the pump and seed radiation. It is shown that, despite a narrowband seed, the generated Stokes pulse spectrum mimics the pump pulse spectral width. The observed SRS conversion efficiency saturates at 40%, with a weak dependence on the seed pulse energy and on the detuning of the pump-seed frequency from the Raman resonance. Theoretical modeling confirms the observed effects and permits prediction of the characteristics of the investigated system as its parameters are varied.