Facile Redox Synthesis and Surface Engineering of Porous Silicon from Zintl Compound for High-Performance Lithium Ion Battery Anodes

Porous silicon (pSi) is considered a promising candidate for next-generation high-energy-density lithium-ion battery (LIB) anodes due to its ability to mitigate volume expansion stress. However, the lack of efficient preparation methods and severe side reactions due to its large specific surface area have hindered its commercial development. This study leverages the redox reaction between the Zintl compound Mg