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September 13, 2024The Journal of Organic Chemistry

Highly Enantioselective Synthesis of Polycyclic Dihydroisoquinolinones via NHC-Catalyzed [4 + 2] Annulations

Xiaojie Ren Xiaoyong Duan Yuxuan Feng Yanting Li Jiahan Li Jing Qi

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The NHC-catalyzed enantioselective [4 + 2] annulation of 9

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Ren et al. (2024) studied this question.

synapsesocial.com/papers/68e58936b6db643587525af5 https://doi.org/10.1021/acs.joc.4c01529

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Nickel-Catalyzed Regio-and Enantioselective [4+2] Annulation towards Synthesis of Axially Chiral Isoquinolinyl and Pyridinyl IsoquinolinonesOriginal Research · 2026
2N-Heterocyclic Carbene (NHC) Catalyzed Annulations of δ-Acetoxy Allenoates and Enaminones: A Time-Controlled Regiodivergent Synthesis of Hexahydroquinolines2025 · 2 citations
3Enantioselective [4 + 2] Annulation Reaction of C1-Ammonium Enolate and Azadiene for 3,4-Dihydroquinolinones SynthesisOriginal Research · 2026 · 3 citations
4Enantioselective Synthesis of Isoquinuclidine Analogs by Synergistic Copper/Amine‐Catalyzed Sequential [3 + 3]/[4 + 2] CycloadditionOriginal Research · 2026 · 2 citations
5Enantioselective Synthesis of Chiral 1,2-Oxazinane Spiro-oxindoles via Carbene-Catalyzed [3+3] Annulation of Isatin-Derived Nitrones with EnalsOriginal Research · 2026

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Enantioselective Synthesis of Isoquinuclidine Analogs by Synergistic Copper/Amine‐Catalyzed Sequential [3 + 3]/[4 + 2] Cycloaddition2026
Synthesis of isoquinoline N-oxides via direct annulation with cyclic dicarbonyls2026
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