An alternative solution to the problem of plastic waste is the development of chemical processes that enable the synthesis of sustainable materials from persistent plastics. The catalytic decomposition of post-consumer HDPE waste by isomerization metathesis (ISOMET) enables the production of propylene, the precursor of allyl acetate. In their Research Article (DOI: 10.1002/chem.202401918), M. Nagyházi, R. Tuba and co-workers recount their development of new ruthenium catalysts that can carry out consecutive olefin metathesis and hydrogenation reactions of allyl acetate to butane-1,4-diol, the precursor of biodegradable and chemically recyclable materials, including polybutylene succinate (PBS).
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Erdélyi et al. (2024) studied this question.
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