Electrodeposition of bismuth, tellurium and bismuth telluride through sub-10 nm mesoporous silica thin films

Templated electrodeposition is an efficient technique for the bottom-up fabrication of nanostructures and can effectively control the size and shape of the electrodeposits.Here, mesoporous silica thin films with highly ordered mesopores and a regular three-dimensional mesostructure were synthesised as templates for electrodeposition.The mesoporous silica films have small mesopores (~8 nm) and complex mesopore channels (Fmmm mesostructure with the [0 1 0] axis perpendicular to the substrate).Electrodeposition of bismuth, tellurium and bismuth-tellurium was investigated from electrolytes containing [N n Bu 4 ][BiCl 4 ], [N n Bu 4 ] 2 [TeCl 6 ] and [N n Bu 4 ]Cl dissolved in dry dichloromethane.Top-view SEM images showed Bi, Te and Bi doped-Te nanoparticles in the mesopores and cross-section SEM showed there were a few Te nanowires, in addition to the particle aggregations on the surface.This is a promising observation as it demonstrates the possibility of preparing sub-10 nm nanowires by templated electrodeposition even though the deposits are not uniformly electrodeposited in all the mesopores.EDX shows the deposited Bi-Te nanoparticles were tellurium-rich, XRD shows they were trigonal tellurium (ICSD 65692).A variety of parameters including the choice of pulsed electrodeposition conditions and [N n Bu 4 ][BiCl 4 ] concentration (2.25 mM and 3 mM) were investigated in order to control the composition of the deposit.All samples prepared by pulsed electrodeposition showed very low Bi:Te ratio (Bi/Te<0.02),whereas samples deposited for 5 min at -0.6 V achieved high Bi content (Bi/Te=0.49).