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Abstract The magnesium chalcogenide spinel MgSc 2 Se 4 with high Mg‐ion room‐temperature conductivity has recently attracted interest as solid electrolyte for magnesium ion batteries. Its ionic/electronic mixed‐conducting nature and the influence of the spinel composition on the conductivity and Mg 2+ migration barrier are yet not well understood. Here, results from a combined experimental and computational study on four MgB 2 Se 4 spinels (B = Sc, Y, Er, Tm) are presented. The room‐temperature ionic conductivities ( σ ion = 2 × 10 −5 –7 × 10 –5 S cm −1 ) of the spinels are accurately measured, as electron transport is effectively suppressed by purely Mg‐ion conducting electrode interlayers. Using the same approach, reversible Mg plating/stripping as well as good electrochemical stability are achieved. Driven by the good accordance of the computationally and experimentally obtained Mg 2+ migration barriers E a (th) and E a , respectively, further periodic density functional calculations are performed on the MgB 2 Se 4 spinel system, revealing the role of trigonal distortion on the migration path geometry and E a (th). These findings provide deeper understanding how to reach small Mg 2+ migration barriers E a in the MgB 2 Se 4 spinels.
Glaser et al. (Tue,) studied this question.