Electrostatic Interaction-Driven Fabrication of Large-Area, Freestanding Nanoparticle Surfactant Membranes with Controllable Elastic Properties

Nanoparticle surfactants assembled at water-oil interfaces can significantly lower the interfacial tension and can be used to stabilize liquids. Understanding and actively tuning the mechanical properties of the generated membranes, which comprise the nanoparticle surfactants, are of significant fundamental interest for the interfacial behavior of nanoparticles and of interest for water purification, drug encapsulation, enhanced oil recovery, and innovative energy transduction applications. Here, we present electrostatic interaction-driven fabrication of freestanding and close-packed SiO