Ge is one of the quintessential semiconductors being considered in nanoform for optoelectronic applications. As a group 14 semiconductor, bulk Ge has a small bandgap and a large Bohr exciton radius, making it an attractive semiconductor for various applications, including solar cell technology, photodetectors, and integrated flash memory devices. I will present our work on doped and alloyed Ge nanoparticles via microwave-assisted synthesis and galvanic replacement. I will present new insights from this chemical route that may impact the nanoparticle synthesis of other covalently bonding semiconductors.
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Susan M. Kauzlarich (2024) studied this question.
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