⌘+K

Pulse Explore Clubs Researchers Journals

Home Clubs Explore

August 7, 2024The Journal of Physical Chemistry A

Theoretical Insights into the Mechanism and Origin of Solvent-Dependent Selectivity in the Cyclization of Propargyl Alcohols for the Divergent Synthesis of N-Heterocycles

Xiuyuan Zou Qing Sun Pan Hong Yuting Xiao Yidong Luo Xin Lü Jin‐Heng Li Ren‐Jie Song

View Full Paper

Ask AI

Bookmark

Share

Abstract

This study elucidates the mechanisms and principles governing chemoselectivity in synthesizing two distinct N-heterocycles, benzimidazole thiazine and benzothiazole imidazole, through BF

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Zou et al. (2024) studied this question.

synapsesocial.com/papers/68e5d34bb6db643587569283 https://doi.org/10.1021/acs.jpca.4c04993

View Full Paper

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Mechanistic Investigation on NHC‐Catalyzed Switchable Annulation Reactions: Polarity Controlled Chemoselective PathwaysOriginal Research · 2026 · 4 citations
2Solvent-Controlled Regioselective [3 + 2] Reactions from Benzofuran-Derived Azadienes and <i>N,N’</i> -Cyclic Azomethine Imines: Synthesis of Two Different Benzofuran Spiro-Fused Bicyclic Pyrazolidine FrameworksOriginal Research · 2026 · 1 citations
3Controlling Product Selectivity by Modulating H-Bonding and the Rate of Hydrogen Elimination and Hydrogen Transfer from an Ir(III)-H ComplexOriginal Research · 2026
4On the Role of the Solvent in the Synthesis of Spirocycles from Alkyne Cations Catalyzed by Triflic Acid: A DFT Study2024 · 1 citations
5Revealing the Role of Solvent in <i>anti</i>-Oxypalladation-Triggered Regiocontrolled Domino Reactions for the Synthesis of Benzazepine- and Tetrahydroquinoline-Containing Scaffolds: A Combined Computational and Experimental Study2024 · 3 citations