Isostructural hydrogen-bonded frameworks based on naphthalene, quinoxaline, and pyrazinopyrazine cores have been constructed. Upon the removal of guest molecules, these three solvated HOFs underwent transformation through the rearrangement of hydrogen bonds. Each transformed structure possesses different intermolecular interactions contributed by the atom in the molecular core. More information can be found in the Research Article by I. Hisaki and co-workers (DOI: 10.1002/chem.202401645).
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