Photoswitchable Catalysis by a Self-Assembled Molecular Cage

Ray G. DiNardi; Samina Rasheed; Simona S. Capomolla; Man Him Chak; Isis A. Middleton; Lauren K. Macreadie; Jake P. Violi; William A. Donald; Paul J. Lusby; Jonathon E. Beves

doi:10.1021/jacs.4c04846

July 25, 2024Journal of the American Chemical SocietyOpen Access

Photoswitchable Catalysis by a Self-Assembled Molecular Cage

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Key Points

Reversible photoswitching regulates catalytic transformations inside a self-assembled coordination cage, enabling remote optical control over substrate conversion.
Light-induced photoisomerization toggles cavity accessibility between active and dormant states, yielding distinct reactivity differences under alternating irradiation cycles.
Supports the rational engineering of stimulus-responsive nanoreactors, while highlighting the broader potential of photoswitchable catalysis for selective synthesis.

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Implication

Experimental study demonstrates reversible photocontrol of catalytic reactions within a self-assembled coordination cage, highlighting new avenues for light-regulated smart nanomaterials.

Abstract

A heteroleptic [Pd

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Cite This Study

DiNardi et al. (2024) studied this question.

synapsesocial.com/papers/68e5f0a2b6db643587585078 https://doi.org/10.1021/jacs.4c04846

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Photoswitchable Catalysis by a Self-Assembled Molecular Cage

Key Points

No abstract yet

Implication

Abstract

Discussion

Cite This Study

Photoswitchable Catalysis by a Self-Assembled Molecular Cage

Key Points

No abstract yet

Implication

Abstract

Discussion

Cite This Study

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