Aims. The line of sight toward Sk 143 (AzV 456), an O9.5 Ib star in the Small Magellanic Cloud (SMC), shows significant absorption from neutral atoms and molecules. We report a new study of this line of sight by means of high-resolution spectra obtained with the ESPRESSO spectrograph at the VLT of ESO. Methods. The absorption from neutral and ionized species is well characterized by a single component at v hel ≈ +132 km s −1 that was modeled with the ASTROCOOK code. Results. The rubidium Rb I 780.0 nm line is detected for the first time outside the Galaxy, and we derive [Rb/H] = −1.86 ± 0.09. As a result of the high resolution, the 85 Rb and 87 Rb isotope lines are also exceptionally well resolved. The 85 Rb/ 87 Rb isotope ratio is 0.46, which is opposite of the meteoritic value of 2.43. This implies that Rb is made through a dominant contribution of the r -process, which is dominant for the 87 Rb isotope. We also confirm the presence of 7 Li I 670.7 nm and set a limit on the isotopic ratio of 6 Li/ 7 Li < 0.1. Conclusions. The dominance of the 87 Rb isotope implies that Rb is made through a dominant contribution of the r -process. At the low metallicity of the cloud of [Zn/H] = −1.28 ± 0.09, neutron rich material may have occurred in rotating metal-poor massive stars. Moreover, the low metallicity of the cloud leads to an absolute Li abundance of A ( 7 Li) ≈ 2.2, which differs from the expectation from big bang nucleosynthesis. Because the gas-phase abundance is not affected by stellar depletion, the burning of Li inside the halo stars is probably not the solution for the cosmological 7 Li problem.
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