A kinetic study of alkali catalyzed hydrolysis of methylpicolinate in aqua-DMSO solvent was done at different temperature (200C, 250C, 300C and 350C) and composition of solvent varying from 10% to 50% (V/V). A depletion in rate of the reaction was found with increase in composition of solvent at all temperatures. To understand the effect of solvent on reaction rate and mechanism iso-composition activation energy, iso-dielectric activation energy and various thermodynamic parameters (∆H*, ∆S* & ∆G*) were evaluated.
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