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June 14, 2024Langmuir6 citations

Antimony-Doped Wide Bandgap Molybdenum Trioxide with Enhanced Localized Surface Plasmon Resonance for Nitrogen Photofixation

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KWKeming WuXidian UniversityZWZheng WangHebei Agricultural UniversityXZXiaonan ZhangJiaying University

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Abstract

Plasmonic metal oxides are promising photocatalysts for the artificial photosynthesis of green ammonia due to localized surface plasmon resonance (LSPR) enhanced photoconversion and rich surface oxygen vacancies improved chemisorption and activation of dinitrogen molecules. However, these oxygen vacancies are unstable during the photocatalytic process and could be oxidized by photogenerated holes, leading to the vanishing of the LSPR. Here, we fabricated antimony-doped molybdenum trioxide nanosheets with stable plasmonic absorption extending into the near-infrared (NIR) range, even after harsh treatment in oxidative atmospheric conditions at high temperatures. For undoped plasmonic MoO

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Cite This Study

Wu et al. (2024) studied this question.

synapsesocial.com/papers/68e64b3cb6db6435875dc127https://doi.org/10.1021/acs.langmuir.4c01135
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