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A modular, operationally practical Ni(0)/silane alkene isomerization system has been developed with air-stable reagents. A diverse array of functional groups are tolerated, including aryl bromides, aromatic heterocycles, tertiary amines, and α,β-unsaturated amides. Mechanistic experiments support a Ni–H insertion/elimination pathway.
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Kascoutas et al. (2024) studied this question.
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