Thiocarbonyl dithiocyanate ( 1 ) and chlorothiocarbonyl thiocyanate ( 2 ) were synthesized from thiophosgene and ammonium or silver thiocyanate, respectivley. Their crystal structures show syn‐anti ( 1 ) and syn ( 2 ) conformations, which were confirmed in the bulk phases by powder X‐ray diffraction, vibrational spectroscopy and DFT calculations. Further calculations explain the isolation of the kinetic reaction products by a lower transition states opposed to the thermodynamic reaction products. Reaction of 1 with ethanol gave a dithiobiuret derivative ( 3 ). In a proof‐of‐principle study we show that it in turn can be used for the complexation of nickel to yield ( 4 ).
No takes yet. Share an insight, caveat, or question.
Pfeiffer et al. (2024) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: