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A Lewis acid-catalyzed intramolecular Hosomi–Sakurai reaction of o-(allylsilyl)benzaldehyde/ketone has been developed. The reaction proceeds through simultaneous C–Si bond cleavage and C–C bond reconstruction. This protocol provides a rapid approach for the synthesis of allyl-substituted benzoxasiloles under mild conditions.
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Yu et al. (2024) studied this question.
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