Enhancing Desorption Performance of a Compressible Hybrid Structured Adsorbent via Localized Magnetic Induction Heating

Structured adsorbents have gained significant importance in gas separation applications due to their ability to fine‐tune mass and heat transfer and lower pressure drop across the bed. This study presents a ferromagnetic compressible hybrid structured adsorbent, allowing regeneration via magnetic induction heating. A compressible melamine sponge is coated with the CO 2 ‐selective Ni‐MOF‐74 adsorbent and Fe 3 O 4 as a ferromagnetic susceptor, capable of dissipating heat instantaneously in an alternating electromagnetic field. Taking advantage of these properties, the potential of rapid CO 2 capture and thermal regeneration via magnetic induction swing adsorption is investigated. The successful incorporation of both ingredients on the melamine sponge is confirmed via SEM‐EDX and XRD analysis. Breakthrough experiments with a CO 2 /CH 4 ‐mixture are performed. The selective property of Ni‐MOF‐74 toward CO 2 is retained, with the composite showing a capacity of 1.89 mmol CO 2 /g. The compressible nature of the melamine sponge allowed for an improvement of 79% in the volumetric capacity of the adsorbent bed and a higher heating rate. In regard to regeneration, within 1 min of subjecting the structured composite to the alternating magnetic field, an efficient desorption (>90%) of CO 2 is achieved. Overall, a ferromagnetic compressible hybrid structured adsorbent is presented for fast cyclic gas‐phase separation processes.