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May 14, 2024Synfacts

gem-Difluorinated Cyclopropanes for α-Fluoro-allylation of Enantioselective Amino Acid Esters

Hisashi Yamamoto Abhijit Paul

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Abstract

Key words α-fluoroallylation - synergistic relay catalysis - Tsuji–Trost reaction - α-quaternary α-amino acid

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Cite This Study

Yamamoto et al. (2024) studied this question.

synapsesocial.com/papers/68e6a3b5b6db6435876270d4 https://doi.org/10.1055/s-0043-1763771

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Enantioselective Tsuji‐Trost α‐Fluoroallylation of Amino Acid Esters with <i>Gem</i>‐Difluorinated Cyclopropanes2024 · 4 citations
2Enantioselective Tsuji‐Trost α‐Fluoroallylation of Amino Acid Esters with <i>Gem</i>‐Difluorinated Cyclopropanes2024 · 49 citations
3Enantioselective Pd/Cu‐Catalyzed Coupling of α‐Azaaryl‐α‐Fluoroesters With <i>gem</i> ‐DifluorocyclopropanesOriginal Research · 2026
4High‐Valent Copper Catalysis Enables Regioselective Fluoroarylation of <i>Gem</i>‐Difluorinated Cyclopropanes2024 · 23 citations
5Selective Fluorination of Multi-Substituted Aldehydes or Ketones Using Amino Catalysts2024

Palladium/Amine Dual-Catalyzed Tsuji–Trost Fluoroallylation of Aldehydes with <i>gem</i>-Difluorinated Cyclopropanes2024
N‐Directed defluorinative <i>γ</i>‐C(sp<sup>3</sup>)−H allylation of sulfamate esters for synthesis of <i>gem</i>‐difluoroalkenes via photoredox catalysis2024
Construction of Fluorinated Tertiary Allylamines via Three-component Photocatalytic Defluorinative Aminoalkylation of gem-Difluoroalkenes2026
Asymmetric [4+2] Photocycloaddition of Aminoquinolines with Styrenes to TetrahydroquinolinesSynfacts · 2026
Electrocatalytic Synthesis of cis-Aziridines via Cobalt CatalysisSynfacts · 2026

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