A T-shaped nickel(I) complex 1 bearing a phenalenyl-based tridentate ligand was synthesized. The electronic and spin struc-tures of 1 were elucidated through electronic absorption spectra, ESR, and XAFS measurements. Additionally, the metallo-radical reactivity of 1 toward diphenyl disulfide and alkyl halides was also demonstrated.
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Noguchi et al. (2024) studied this question.
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