State-of-the-art strategies for alkene-hydroxyazidation, which yield a mixture of β-azido alcohol and β-azido peroxide, must rely on phosphine reagents to improve the chemoselectivity. To overcome the above problems, we present a photochemical hydroxyazidation of alkenes via Mn-mediated ligand-to-metal charge transfer (LMCT) in O
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Xia et al. (2024) studied this question.
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