Rh complexes of a tridentate PPP ligand bearing 1,2-pyrrolediyl linkers have been prepared, including examples with the central P donor being either a phosphine or a phosphide. Three bimetallic Rh complexes containing the diamandoid Rh2P2 core (P = phosphido) have been structurally and spectroscopically characterized. The Rh–Rh interaction in these three dimers was examined by way of structural comparisons and DFT investigations.
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Cosio et al. (2024) studied this question.
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