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Sensors for quantitative monitoring of greenhouse gases from high-emission facilities, such as wastewater treatment and industrial plants, are becoming essential to enforce regulatory compliance in climate action initiatives. A predominant sensing technique is the tracer-gas dispersion method (TDM) using closed-path gas analyzers typically installed in a vehicle to measure concentration as the gas plume is transected. Here, we validate for the first time the use of integrated-path gas sensors in TDM, measuring instantaneously the concentration along a predetermined laser beam path, thereby facilitating a stationary setup with orders of magnitude higher update rate and without the need for vehicles or road access. Our approach relies on a sensitive, integrated-path multi-gas sensor for real-time emission quantification using tunable diode laser absorption spectroscopy. An optical sensor head with spectral coverage from 1.52 μm to 1.65 μm is demonstrated, supporting multiplexed gas sensing in a modular fashion using low-power fiber-coupled diode lasers. The sensor measures real-time integrated-path concentrations of CO2 and CH4, and the tracer-gas C2H2 at 130 Hz with 0.5 ppm, 3 ppb, and 2 ppb sensitivity, respectively, at 1 s averaging. The integrated-path sensor is systematically benchmarked for absolute accuracy against a state-of-the-art point sensor, revealing an excellent match over 16 hours. Furthermore, the integrated-path sensor is deployed outdoors for emission quantification using TDM. A comparison to the gold-standard point sensor reveals identical results, demonstrating the integrated-path sensor as a potent substitute for vehicle-driven point sensors.
Ashik et al. (Sun,) studied this question.