Preparation of Ti3C2Tx modified rare earth doped PbO2 electrodes for efficient removal of sulfamethoxazole

In this study, we deposited Ti 3 C 2 T x -modified, rare-earth-doped PbO 2 on the surface of a carbon fabric via electrodeposition. The surface morphology and electronic structure of the electrode were characterized with SEM, XRD and XPS. The layered Ti 3 C 2 T x did not change the structure of β-PbO 2 , and at the same time, it improved the crystallinity of the material and reduced the grains of PbO 2 . Electrochemical experiments showed that the addition of Ti 3 C 2 T x increased the electrochemical activity of the electrode and produced more H 2 O 2 , which contributed to the degradation of pollutants. The efficiency of sulfamethoxazole (SMX) degradation reached 95% after 120 min at pH 3 with a current density of 50 mA/cm 2 . Moreover, the electrode has good cycling performance, and the degradation efficiency was still 80% after 120 min after 10 cycles of recycling. Based on the intermediates identified by HPLC‒MS, a mechanism for SMX degradation was proposed. Our results will provide a new idea for the development of efficient electrocatalytic degradation of antibiotics.