This is the authors' abstract. We don't add key points for this paper.
The development of a new class of concave P-stereogenic phosphorodiamidite ligands, derived from Tröger's bases (TBs), is explored. These ligands, characterized by their remarkable stability and unique structural geometry around the P atom, are used in asymmetric Rh(I)-catalyzed additions of boronic acids to NH-isatins resulting in excellent reactivities and reasonable enantioselectivity (er up to 92:8).
Answers are grounded in this paper and cite their sources.
No takes yet. Share an insight, caveat, or question.
Saleh et al. (2024) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: