Laboratory studies and modelling of ferric chloride as the cause of the anomalous UV absorption in the Venusian atmosphere

The cause of the inhomogeneous near-ultraviolet absorption observed in the upper clouds of Venus remains a key question in Venusian research. One possible candidate in the literature is ferric chloride. The absorption spectrum of ferric chloride currently in use by models uses ethyl acetate as a solvent and does not reproduce the absorption features observed on Venus. The study of the optical properties and chemistry of ferric chloride in the sulphuric acid cloud droplets is required to draw valid conclusions regarding its suitability as a candidate for the near-UV absorption. In this study, we measure the absorption spectrum of ferric chloride in sulphuric acid from 200 – 600 nm at a range of temperatures and measure the rate of conversion of the ferric chloride ions into ferric sulphate ions. We then use the resulting ferric chloride absorption coefficients in a 1D radiative transfer model and estimate the required concentration of ferric chloride in the clouds to be 0.6 – 0.9 wt% in the mode 1 (~0.3 µm radius) cloud droplets to match observations. We also predict the atmospheric concentrations of ferric chloride formed from the reaction of iron ablating from cosmic dust entering Venus’ atmosphere around 120 km with hydrogen chloride emitted by volcanic activity, and estimate the accumulation timescale of ferric chloride to produce the required concentrations in the clouds.