⌘+K

Pulse Explore Communities Researchers Journals

Home Communities Explore

February 14, 2024Synfacts

Aryne-Activated Smiles Rearrangement of Anilines

Dahui Zhao Xiaohan Wan

View at Publisher

Ask AI

Bookmark

Share

Abstract

Key words metal-free protocol - arynes - aniline - biaryl synthesis - C–N arylation - Smiles–Truce rearrangement

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Zhao et al. (2024) studied this question.

synapsesocial.com/papers/68e79403b6db643587704aeb https://doi.org/10.1055/s-0043-1773031

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Photoinduced Smiles Rearrangement of <i>N</i> -Sulfonylpropargylamines for Highly Stereoselective Access to Tetrasubstituted AllylaminesOriginal Research · 2026 · 3 citations
2Metal-free strategy for C–N cross-coupling of benzamide with sulfonamide enabled by a Smiles rearrangementOriginal Research · 2026
3Access to Biaryls via Anilide C–N Bond Activation through Photocatalytic Radical Truce–Smiles RearrangementOriginal Research · 2025 · 5 citations
4A truce on the Smiles rearrangement: revisiting an old reaction—the Truce–Smiles rearrangementReview · 2008 · 205 citations
5Cascade Aryne Aminoarylation for Biaryl Phenol Synthesis2024 · 11 citations

More related papers

Merging Hydrogen-Atom-Transfer and the Truce-Smiles Rearrangement for Synthesis of beta-Arylethylamines from Unactivated Allylsulfonamides2024
<i>meta</i>-Substituted Diaryliodonium Salts Enabled Aryne 1,2,4′-Trifunctionalization2025
Photoinduced Synthesis of α-Aryl-β-arylthiopropanamide from <i>N</i> -(Arylsulfonyl)methacrylamide <i>via</i> Smiles Rearrangement2026

More from Synfacts

Asymmetric [4+2] Photocycloaddition of Aminoquinolines with Styrenes to TetrahydroquinolinesWed,
Electrocatalytic Synthesis of cis-Aziridines via Cobalt CatalysisWed,