Observation shows the role of nonequilibrium dynamics in creating dimethyl ether from methanol, indicating a quasi-integrable regime.
Ionization of carbene–methanol clusters with electron recombination yields dimethyl ether via roaming. Nonequilibrium energy partitioning drives roaming, suppressing energy exchange and enabling a quasi-integrable regime.
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Toshiaki Matsubara (2025) studied this question.
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