This analysis contrasts kinetic control with thermodynamic control during enolization of 1-methylcyclohexanone, suggesting important implications for reaction pathways.
The concept of kinetic vs thermodynamic control of a reaction is often taught in the context of the enolisation of e.g. 1-methylcyclohexanone as induced by a base.
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Henry S. Rzepa (2013) studied this question.
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