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October 11, 2025The Journal of Chemical Physics2 citationsOpen Access

Entropy of self-avoiding branching polymers: Mean-field theory and Monte Carlo simulations

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DMDavide MarcatoAGAchille GiacomettiAMAmos Maritan

Key Points

  • The mean number of branch nodes is determined independent of lattice structure or occupation, relying solely on chemical potential.
  • Mean-field theory results align closely with Monte Carlo simulations, particularly in higher dimensions (d = 2, 3, and 4).
  • We leverage the statistical model of rooted-directed trees for computation within a thermodynamic limit.
  • This work enhances understanding of the entropy involved in complex branching polymer structures.

Abstract

We study the statistics of branching polymers with excluded-volume interactions, by modeling them as single self-avoiding trees on a generic regular periodic lattice with coordination number q. Each lattice site can be occupied at most by one tree node, and the fraction of occupied sites can vary from dilute to dense conditions. By adopting the statistics of rooted-directed trees as a proxy for that of undirected trees without internal loops and by an exact mapping of the model into a field theory, we compute the entropy and the mean number of branch nodes within a mean-field approximation and in the thermodynamic limit. In particular, we find that the mean number of branch nodes is independent of both the lattice details and the lattice occupation, depending only on the associated chemical potential. Monte Carlo simulations in d = 2, 3, 4 provide evidence of the remarkable accuracy of the mean-field theory, more accurate for higher dimensions.

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Cite This Study

Marcato et al. (2025) studied this question.

synapsesocial.com/papers/68e9b1c1ba7d64b6fc13229bhttps://doi.org/10.1063/5.0287899
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