External oxidant-free heterogeneous gold-catalyzed C(sp 2 )-C(sp 2 ) cross-coupling of aryldiazonium salts and arylboronic acids with the assistance of bpy ligand

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This is a Experimental Study study.

Ling Chen; Boling Song; Jiajia Li; Mingzhong Cai

doi:10.1039/d5dt01711d

January 1, 2025Dalton Transactions

External oxidant-free heterogeneous gold-catalyzed C(sp 2 )-C(sp 2 ) cross-coupling of aryldiazonium salts and arylboronic acids with the assistance of bpy ligand

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Key Points

Cross-coupling reactions achieved effective coupling of aryldiazonium salts and arylboronic acids.
Utilizing the mesoporous SBA-15-supported gold catalyst leads to enhanced efficiency in these chemical transformations.
The designed gold(I) complex was synthesized via a straightforward immobilization method.
Characterization confirmed the efficacy of the catalyst in facilitating oxidant-free reactions.

Implication

This research reveals a novel gold-catalyzed cross-coupling method using aryldiazonium salts and arylboronic acids, highlighting efficient reactions with bpy ligand.

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Cite This Study

Chen et al. (2025) studied this question.

synapsesocial.com/papers/68e9b2e4ba7d64b6fc1330d7 https://doi.org/10.1039/d5dt01711d

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External oxidant-free heterogeneous gold-catalyzed C(sp 2 )-C(sp 2 ) cross-coupling of aryldiazonium salts and arylboronic acids with the assistance of bpy ligand

Key Points

Implication

Abstract

Discussion

Cite This Study

External oxidant-free heterogeneous gold-catalyzed C(sp 2 )-C(sp 2 ) cross-coupling of aryldiazonium salts and arylboronic acids with the assistance of bpy ligand

Key Points

Implication

Abstract

Discussion

Cite This Study

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