Multi-Technique Characterization of Rhodium Gem-Dicarbonyls on TiO₂(110)

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This is a Experimental Study study.

Moritz Eder; Faith J. Lewis; Johanna Hütner; Panukorn Sombut; Maosheng Hao; David Rath; Paul Ryan; Jan Balajka; M. Wagner; Matthias Meier; Cesare Franchini; Gianfranco Pacchioni; Ulrike Diebold; Michael Schmid; Florian Libisch; Jiří Pavelec; Gareth S. Parkinson

doi:10.1039/d5sc04889c

January 1, 2025Chemical ScienceOpen Access

Multi-Technique Characterization of Rhodium Gem-Dicarbonyls on TiO₂(110)

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Key Points

Detection of rhodium gem-dicarbonyls using multiple techniques provides new insights into their behavior on surfaces.
Infrared spectroscopy effectively identifies these species, demonstrating its utility in catalysis studies.
Research focuses on metal oxide surfaces, indicating their importance in the catalytic processes under investigation.
Understanding these intermediates is crucial for advancing applications in heterogeneous catalysis.

Implication

Analysis reveals detection of rhodium gem-dicarbonyls on TiO2 surfaces, suggesting enhanced methods for heterogeneous catalysis.

Abstract

Gem-dicarbonyls of transition metals supported on metal (oxide) surfaces are common intermediates in heterogeneous catalysis. While infrared (IR) spectroscopy is a standard tool for detecting these species on powder catalysts,...

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Cite This Study

Eder et al. (2025) studied this question.

synapsesocial.com/papers/68f3d0c11cb4135751d12bdc https://doi.org/10.1039/d5sc04889c

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Multi-Technique Characterization of Rhodium Gem-Dicarbonyls on TiO₂(110)

Key Points

Implication

Abstract

Discussion

Cite This Study

Multi-Technique Characterization of Rhodium Gem-Dicarbonyls on TiO₂(110)

Key Points

Implication

Abstract

Discussion

Cite This Study

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